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Journal / Chemistry / 稳定笼 Aziridinium 离子的制备及其开环 Azaheterocycles…
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JoVE Journal Chemistry
稳定笼 Aziridinium 离子的制备及其开环 Azaheterocycles 的合成
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稳定笼 Aziridinium 离子的制备及其开环 Azaheterocycles 的合成

Article DOI: 10.3791/57572-v • 11:45 min • August 22nd, 2018
August 22nd, 2018 •
1, 2
1Department of Chemistry, North Eastern Regional Institute of Science and Technology, 2Department of Chemistry, Hankuk University of Foreign Studies

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笼 aziridinium 离子, 如 1-azoniabicyclo [4.1. 0] 庚烷磺酸盐是由 2-[4-tolenesulfonyloxybutyl] 氮丙啶, 用于制备替代的 piperidines 和 azepanes 通过地-和立体环形膨胀与各种亲核试剂。这一高效的协议允许我们准备各种 azaheterocycles, 包括自然产品, 如 fagomine, febrifugine 模拟和 balanol。

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化学 问题 138 笼 aziridinium 离子 环形膨胀 立体 azaheterocycles piperidines azepane
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